529-0440-00L  Physical Electrochemistry and Electrocatalysis

SemesterSpring Semester 2016
LecturersT. Schmidt
Periodicityyearly recurring course
Language of instructionEnglish


AbstractFundamentals of electrochemistry, electrochemical electron transfer, electrochemical processes, electrochemical kinetics, electrocatalysis, surface electrochemistry, electrochemical energy conversion processes and introduction into the technologies (e.g., fuel cell, electrolysis), electrochemical methods (e.g., voltammetry, impedance spectroscopy), mass transport.
ObjectiveProviding an overview and in-depth understanding of Fundamentals of electrochemistry, electrochemical electron transfer, electrochemical processes, electrochemical kinetics, electrocatalysis, surface electrochemistry, electrochemical energy conversion processes (fuel cell, electrolysis), electrochemical methods and mass transport during electrochemical reactions. The students will learn about the importance of electrochemical kinetics and its relation to industrial electrochemical processes and in the energy seactor.
ContentReview of electrochemical thermodynamics, description electrochemical kinetics, Butler-Volmer equation, Tafel kinetics, simple electrochemical reactions, electron transfer, Marcus Theory, fundamentals of electrocatalysis, elementary reaction processes, rate-determining steps in electrochemical reactions, practical examples and applications specifically for electrochemical energy conversion processes, introduction to electrochemical methods, mass transport in electrochemical systems. Introduction to fuel cells and electrolysis
Lecture notesWill be handed out during the Semester
LiteraturePhysical Electrochemistry, E. Gileadi, Wiley VCH
Electrochemical Methods, A. Bard/L. Faulkner, Wiley-VCH
Modern Electrochemistry 2A - Fundamentals of Electrodics, J. Bockris, A. Reddy, M. Gamboa-Aldeco, Kluwer Academic/Plenum Publishers