From 2 November 2020, the autumn semester 2020 will take place online. Exceptions: Courses that can only be carried out with on-site presence. Please note the information provided by the lecturers via e-mail.

529-0012-01L  Physical Chemistry I: Thermodynamics

SemesterSpring Semester 2016
LecturersF. Merkt
Periodicityyearly recurring course
Language of instructionGerman


AbstractFoundations of chemical thermodynamics. The first, second and third law of thermodynamics: Thermodynamic temperature scale, internal energy, enthalpy, entropy, the chemical potential. Solutions and mixtures, phase diagrams. Reaction thermodynamics: reaction parameters and equilibrium conditions, equilibrium constants. Thermodynamics of processes at surfaces and interfaces.
ObjectiveIntroduction to chemical thermodynamics
ContentThe first, second and third law of thermodynamics: empirical temperature and thermodynamic temperature scale, internal energy, entropy, thermal equilibrium. Models and standard states: ideal gases, ideal solutions and mixtures, real gases, real solutions and mixtures, activity, tables of standard thermodynamic quantities. Reaction thermodynamics: the chemical potential, reaction parameters and equilibrium conditions, equilibrium constants and their pressure and temperature dependence. Phase equilibria. Thermodynamics at surfaces and interfaces: Adsorption equilibria. Capillary forces. Adsorption isothermes.
Lecture notesIn preparation.
LiteratureA list of possible text books will be provides as separate documents in the lecture.
Prerequisites / NoticeVoraussetzungen: Allgemeine Chemie I, Grundlagen der Mathematik