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529-0012-03L  General Chemistry (Organic Chemistry) II

SemesterSpring Semester 2016
LecturersP. Chen, A. Bach
Periodicityyearly recurring course
Language of instructionGerman


AbstractClassification of organic reactions, reactive intermediates: radicals, carbocations, carbanions, organic acids / bases, electronic substituent effects, electrophilic aromatic substitution, electrophilic addition to double bonds, HSAB concept, nucleophilic substitution at sp3 hybridized carbon centres (SN1/SN2 reactions), nucleophilic aromatic substitutions, eliminations.
ObjectiveUnderstanding of fundamental reactivity principles and the relationship between structure and reactivity. Knowledge of the most important raection types and of selected classes of compounds.
ContentClassification of organic reactions, reactive intermediates: radicals, carbocations, carbanions, organic acids / bases, electronic substituent effects, electrophilic aromatic substitution, electrophilic addition to double bonds, HSAB concept, nucleophilic substitution at sp3 hybridized carbon centres (SN1/SN2 reactions), nucleophilic aromatic substitutions, eliminations.
Lecture notespdf file available at the beginning of the course
Literature[1] P. Sykes, "Reaktionsmechanismen der Organischen Chemie", VCH Verlagsgesellschaft, Weinheim 1988.
[2] Carey/Sundberg, Advanced Organic Chemistry, Part A and B, 3rd ed., Plenum Press, New York, 1990/1991. Deutsch: Organische Chemie.
[3] Vollhardt/Schore, Organic Chemistry, 2th ed., Freeman, New York, 1994 Deutsche Fassung: Organische Chemie 1995, Verlag Chemie, Wein¬heim, 1324 S. Dazu: N. Schore, Arbeitsbuch zu Vollhardt, Organische Chemie, 2. Aufl. Verlag Chemie, Weinheim, 1995, ca 400 S.
[4] J. March, Advanced Organic Chemistry; Reactions, Mechanisms, and Structure, 5th ed., Wiley, New York, 1992.
[5] Streitwieser/Heathcock, Organische Chemie, 2. Auflage, Verlag Chemie, Weinheim, 1994.
[6] Streitwieser/Heathcock/Kosower, Introduction to Organic Chemistry, 4th ed., MacMillan Publishing Company, New York, 1992.
[7] P. Y. Bruice, Organische Chemie, 5. Auflage, Pearson Verlag, 2007.